Product ID:ANTIFREEZE AND COOLANT, 0161
MSDS Date:02/12/1996
FSC:6850
NIIN:00-664-1403
MSDS Number: CDZTZ

CITGO PETROLEUM CORP

TULSA, OK 74102
US

Emergency Phone: 918-495-4700; 800-424-9300

Info Phone: 918-495-5933

Cage: 1JW40

CITIES SERVICE RESEARCH AND DEVELOPMENT

300 TULSA, OK 74102 US

Telephone: 918-561-5165

Cage: 73589

ETHYLENE GLYCOL (SARA 313) (CERCLA)

CAS: 107-21-1

RTECS: KW2975000

Fraction By Weight: 90-95%

OSHA PEL N/K

ACGIH TLV: 50 PPM, VAPOR, C

EPA Report Quantity: 1 LB

DOT Report Quantity: 1 LB

DIETHYLENE GLYCOL

CAS: 111-46-6

RTECS: ID5950000

Fraction By Weight: 0-5%

OSHA PEL N/K

ACGIH TLV: N/K

POTASSIUM PHOSPHATE; DIBASIC; (DIPOTASSIUM PHOSPHATE)

CAS: 7758-11-4

Fraction By Weight: <5%

OSHA PEL N/K

ACGIH TLV: N/K

ADDITIVES AND OTHER INGREDIENTS; (ADDITIVES AND DYES)

Fraction By Weight: <5%

OSHA PEL N/K

ACGIH TLV: N/K

MAY BE EXPECTED 24-72 HRS AFTER INGEST.

RTECS: 9999999ZZ

ETHYLENE GLYCOL HAS PRDCED

RTECS: 9999999ZZ

ON EFTS OF CHRONIC INHAL EXPOS TO ETHYLENE GLYCOL IN

RTECS: 9999999ZZ

WORKERS EXPOS TO 49PPM OF ETHYLENE GLYCOL OVER

RTECS: 9999999ZZ

VAPS PRDCED SEV IRRIT IN RABBITS &

RTECS: 9999999ZZ

RSLTD IN KIDNEY DMG, OFTEN W/DEPOSITS OF CALCIUM

RTECS: 9999999ZZ

ETHYLENE GLYCOL IN DRINKING WATER. CALCIUM OXALATE

RTECS: 9999999ZZ

PRDCED ACCUM OF GLYCOLATE & GLYOXALATE WHICH FORM

RTECS: 9999999ZZ

FAILURE & PULM EDEMA. RPTS OF KIDNEY INSUFFICIENCY

RTECS: 9999999ZZ

BY ACCUM OF CALCIUM OXALATE CRYSTALS. CRYSTALLURIA

RTECS: 9999999ZZ

USE OF PERSONAL PROT EQUIP. CNTN SPILL IN

RTECS: 9999999ZZ

RECOVERY. DO NOT ALLOW MATL TO ESCAPE INTO SEWERS,

RTECS: 9999999ZZ

RELEASES AS REQD BY LAW TO APPROP STATE & FEDERAL

RTECS: 9999999ZZ

FED, STATE & LOCAL AUTHS BEFORE REUSING,

RTECS: 9999999ZZ

OF EMPTY CNTNRS &/OR WASTE RESIDUAL OF THIS

RTECS: 9999999ZZ

REMOVE CONTAMD CLTHG. LAUNDER BEFORE REUSE.

RTECS: 9999999ZZ

UNNECESSARY PERSONS FROM HAZARD AREA.

RTECS: 9999999ZZ

LEVELS AS EVALUATED BY DESIGNATED PERSONNEL.

RTECS: 9999999ZZ

BUTYL RUBBER, NATURAL RUBBER, NEOPRENE,

RTECS: 9999999ZZ

LD50 LC50 Mixture:NONE SPECIFIED BY MANUFACTURER.
Routes of Entry: Inhalation:YES Skin:YES Ingestion:YES
Reports of Carcinogenicity:NTP:NO IARC:NO OSHA:NO
Health Hazards Acute and Chronic:ACUTE: INHAL:SEV RESP IRRITANT. IN GEN
EFTS BECOME NOTICEABLE W/AIRBORNE CONC OF APPROX 60PPM. COUGH &
BURNING SENSATION IN TRACHEA ARE SYMPS OF EXPOS ABOVE 80PPM. CNS
DEPRESSANT; SYMPS INCL HDCH, WEA K, NAUS, DIZZ, LOSS OF JUDGMENT &
COORD. COMA & DEATH AT HIGH CONCS ARE POSS. SKIN:IRRITANT & MAY BE
(EFTS OF OVEREXP)
Explanation of Carcinogenicity:NOT RELEVANT
Effects of Overexposure:HLTH HAZ:ABSORBED THRU SKIN. EYE:MAY RSLT IN
IMMED DISCOMFORT W/MILD TEMPORARY CONJ INFLAM; PERM DMG NOT ANTIC.
INGEST:PREDOMINANT HAZ IS ASSOC W/INGEST OF LG QTYS AT SINGLE TIME.
DURING FIRST 12 HRS, MAY EXPERIENCE CNS EFTS SUCH AS HDCH, WEAK,
NAUS, DIZZ, LOSS OF JUDGMENT & COORD. IN MILD CASES, APPEARS DRUNK
(SUPDAT)
Medical Cond Aggravated by Exposure:PREEXISTING KIDNEY DISEASE.

First Aid:INHAL:MOVE TO FRESH AIR. ADMIN CPR & O*2 AS NEC. SEEK MED
ATTN IMMED. SKIN: RINSE EXPOS AREA W/WATER. REMOVE CONTAMD CLTHG;
WASH BEFORE REUSE. SEEK MED ATTN IF IRRIT IS SERIOUS OR PERSISTS.
EYES:IMMED WASH W/LG AMTS OF WATER FOR @ LST 15 MIN, OCCASNLY
LIFTING LIDS. SEEK MED ATTN IMMED. INGEST:GIVE 2 GLASSES OF WATER &
INDUCE VOMIT. SEEK MED ATTN IMMED. NOTE TO MD:INGEST OF ETHYLENE
GLYCOL (ING 12)

Flash Point:250F,121C
Lower Limits:3.2%
Extinguishing Media:FOR SMALL FIRES USE DRY CHEMICAL OR CARBON DIOXIDE.
FOR LARGE FIRES USE WATER SPRAY, FOG OR FOAM.
Fire Fighting Procedures:USE NIOSH APPROVED SCBA AND FULL PROTECTIVE
EQUIPMENT . USE WATER SPRAY OR FOG NOZZLE TO KEEP CONTAINERS COOL.
VENTILATE ENCLOSED AREAS BEFORE ENTERING.
Unusual Fire/Explosion Hazard:ETHYLENE GLYCOL PRESENTS A MODERATE
EXPLOSION HAZARD WHEN EXPOSED TO FLAME AND AIR.

Spill Release Procedures:REMOVE ALL HEAT & IGNIT SOURCES. ISOLATE AREA
& RESTRIC ACCESS TO PERS WEARING PROT EQUIP. SM SPILL:ABSORB MATL
W/NON-COMBUST ABSORB. PLACE INTO CNTNRS FOR DISP. LG
SPILLS:EVACUATE AREA. ADEQUATELY VE NT & DETERM POTNTL EXPOS
CNDTNS; MAY REQ (ING 15)
Neutralizing Agent:NONE SPECIFIED BY MANUFACTURER.

Handling and Storage Precautions:DO NOT APPLY HIGH HEAT/FLAME TO CNTNR.
PROD MAY CAUSE SLIPPERY CNDNTS ON WALKING SURFS IF SPILLED.
PRACTICE REASONABLE CARE. CONSULT APPROP (ING 18)
Other Precautions:DURING REPAIR & MAINT OF CONTAMD EQUIP:DRAIN & PURGE
EQUIP AS NEC TO REMOVE MATL RESIDUES. USE IMPERVIOUS GLOVES (BUTYL
RUB, NATRL RUB, NEOPRENE OR NITRILE RUB) & PROT WORK CLTHG IF
DIRECT CNTCT IS AN TIC. ELIM HEAT & IGNIT SOURCES. (ING 20)

Respiratory Protection:ONLY NIOSH APPRVD ORGANIC VAPOR & DUST/MIST
RESPIRATORS SHOULD BE USED. FOR AIRBONE CONCS AT OR ABOVE 500 PPM,
SUPPLIED-AIR RESPIRATOR OR SCBA W/FULL FACE MASK MUST BE USED.
RESPIRATORY PROT SHOULD BE SELECTED ON BASIS OF MAX ANTIC CONC.
Ventilation:IN CONFINED SPACE, MECH VENT MAY BE REQD TO KEEP LEVELS OF
CERTAIN COMPONENTS BELOW APPLIC WORKPLACE EXPOSURE (ING 22)
Protective Gloves:WORK GLOVES CONSTRUCTED OF (ING 23)
Eye Protection:ANSI APPRVD CHEM WORKERS GOGGLES .
Other Protective Equipment:ANSI APPRVD EYE WASH & DELUGE SHOWER . FULL
BODY PROTECTIVE WORK CLTHG. LAUNDER CONTAMD WORK CLOTHES BEFORE
REUSE.
Work Hygienic Practices:GARMENTS CONTAMINATED W/PRODUCT SHOULD BE
CHANGED. SHOWER W/SOAP & WATER TO REMOVE ANY RESIDUES FROM SKIN.
Supplemental Safety and Health
SPEC GRAV: 1.11-1.14 (H*2O=1). PH (50% BY VOL): 10-11. CNDTNS TO AVOID:
PHOSPHORUS PENTASULFIDE. EFTS OF OVEREXP:W/OUT BRTH OF ALCOHOL. IN
MORE SEV CASES, CONVLS & COMA. FOLLOWED BY CARDIOPULM SYMPS I NCL
MILD HYPERTENSION, ABNORM FAST HEARTBEAT & BRTHG RATE. KIDNEY
COMPLICATIONS INCL SLOW/NO URINE PRODUCTION, (ING 5)

Boiling Pt:B.P. Text:259F,126C
Melt/Freeze Pt:M.P/F.P Text:-35F,-37C
Vapor Pres:0.05
Vapor Density:2.14
Spec Gravity:SUPDAT
pH:SUPDAT
Evaporation Rate & Reference:<0.002 (BUTYL ACETATE=1)
Solubility in Water:SOLUBLE
Appearance and Odor:BLUE-GREEN LIQUID; ODORLESS.

Stability Indicator/Materials to Avoid:YES
STRONG OXIDIZERS. ETHYLENE GLYCOL IGNITES ON CNTCT W/CHROMIUM TRIOXIDE,
POTASSIUM PERMANGANATE OR SODIUM PEROXIDE.
Stability Condition to Avoid:ETHYLENE GLYCOL CAN REACT VIOLENTLY
W/CHLORSULFONIC ACID, OLEUM, SULFURIC ACID, PERCHLORIC ACID, NITRIC
ACID & (SUPDAT)
Hazardous Decomposition Products:WHEN HEATED TO DECOMP TEMPS, THIS MATL
EMITS CARBON MONOXIDE, CARBON DIOXIDE & IRRITATING & ACRID FUMES.

Waste Disposal Methods:TREATMENT, STORAGE, TRANSPORTATION & DISPOSAL
MUST BE IN ACCORDANCE W/APPLICABLE FEDERAL, STATE AND LOCAL
REGULATIONS. CONTACT RCRA/SUPERFUND HOTLINE AT 1-800-424-9346 OR
REGIONAL UP EPA OFFICE FOR GU IDANCE CONCERNING CASE SPECIFIC
DISPOSAL ISSUES.

Disclaimer (provided with this information by the compiling agencies):
This information is formulated for use by elements of the Department
of Defense. The United States of America in no manner whatsoever,
expressly or implied, warrants this information to be accurate and
disclaims all liability for its use. Any person utilizing this
document should seek competent professional advice to verify and
assume responsibility for the suitability of this information to their
particular situation.